Tungsten(IV) telluride

Tungsten(IV) telluride

250px WTe2 has a layered crystal structure with two different W sites
Names
Other names tungsten ditelluride
Identifiers
CAS Number	12067-76-4 Y
EC Number	235-086-0
Jmol 3D model	Interactive image
PubChem	82913
InChI InChI=1S/2Te.W
SMILES [Te]=[W]=[Te]
Properties
Chemical formula	WTe2
Molar mass	439.04 g/mol
Appearance	gray crystals
Density	9.43 g/cm3, solid
Melting point	1,020 °C (1,870 °F; 1,290 K)
Structure
Crystal structure	orthorhombic, oP12
Space group	Pmn21, No. 31
Vapor pressure	{{{value}}}
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Tungsten(IV) telluride (WTe₂) is an inorganic semimetallic chemical compound. In October 2014, tungsten ditelluride was discovered to exhibit an extremely large magnetoresistance: 13 million percent with no known saturation point. The resistance is proportional to the square of the magnetic field. This may be due to the material being the first example of a compensated semimetal, in which the number of mobile holes is the same as the number of electrons. The structure of tungsten ditelluride is layered, and the substance can be exfoliated into thin sheets down to monolayers. However electrons can easily move between the layers, unlike in other two dimensional semiconductors. The fraction of charge carriers is 0.005 per formula unit (WTe₂).

When subjected to pressure, the magnetoresistance effect in WTe₂ is reduced. At a pressure of 10.5 GPa magnetoresistance disappears. Above this same pressure of 10.5 GPa tungsten ditelluride can become a superconducter. At 13.0 GPa the transition to superconductivity happens below 6.5K. WTe₂ was also recently predicted to be a Weyl semimetal and, in particular, to be the first example of a "Type II" Weyl semimetal, where the Weyl nodes exist at the intersection of the electron and hole pockets.