Thiete
From Infogalactic: the planetary knowledge core
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Names | |
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IUPAC name
2H-thiete
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Identifiers | |
Jmol 3D model | Interactive image |
PubChem | 3415867 |
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Properties | |
C3H4S | |
Molar mass | 72.12886 |
Vapor pressure | {{{value}}} |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references | |
Thiete is a heterocyclic compound containing an unsaturated four-membered ring with three carbon atoms and one sulfur atom.[1][2][3] It is more commonly encountered not on its own, but in anellated derivatives, several of which have been synthesized. Thietes are generally not very stable.[4]
Structure
Thiete is a valence isomer of the unknown compound thioacrolein (CH2=CHCH=S) Thiete has been shown to be planar, with a C-S-C angle of 76.8 degrees.[5]
Thiete 1,1-dioxides
Thiete 1,1-dioxides are sulfones, the parent being C3H4SO2. They are more stable than thietes themselves.[6] Substituted thiete-1,1-dioxides can also be prepared by [2+2] cycloaddition of sulfenes and ynamines.
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References
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- ↑ Thomas C. Sedergran and Donald C. Dittmer "Thiete 1,1-dioxide and Chlorothiete 1,1-dioxide" Org. Synth. 1984, vol. 62, 210.doi:10.15227/orgsyn.062.0210
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- Sulfur heterocycles