Tetrabromoethane

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Tetrabromoethane
Seletal formula of tetrabromoethane
Stereo, skeletal formula of tetrabromoethane with all explicit hydrogens added
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Spacefill model of tetrabromoethane
Names
IUPAC name
1,1,2,2-Tetrabromoethane[2]
Other names
Identifiers
79-27-6 YesY
Abbreviations TBE[1]
1098321
ChemSpider 6339 N
EC Number 201-191-5
Jmol 3D model Interactive image
MeSH 1,1,2,2-tetrabromoethane
PubChem 6588
RTECS number KI8225000
UN number 2504
  • InChI=1S/C2H2Br4/c3-1(4)2(5)6/h1-2H N
    Key: QXSZNDIIPUOQMB-UHFFFAOYSA-N N
  • BrC(Br)C(Br)Br
Properties
C2H2Br4
Molar mass 345.65 g·mol−1
Appearance Colourless liquid
Density 2.967 g mL−1
Melting point −1.0 °C; 30.3 °F; 272.2 K
Boiling point 243.6 °C; 470.4 °F; 516.7 K
630 mg L−1 (at 20 °C)
Vapor pressure 10 Pa (at 20 °C)
1.637
Thermochemistry
165.7 J K−1 mol−1
Vapor pressure {{{value}}}
Related compounds
Related alkanes
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Tetrabromoethane (TBE) is a halogenated hydrocarbon, chemical formula C2H2Br4. Although three bromine atoms may bind to one of the carbon atoms creating 1,1,1,2-tetrabromoethane this is not thermodynamically favorable, so in practice tetrabromoethane is equal to 1,1,2,2-tetrabromoethane, where each carbon atom binds two bromine atoms.

It has an unusually high density for an organic compound, near 3 g/mL, due largely to the four bromine atoms.[3] TBE is a liquid at room temperature, and is used to separate mineral ores from its supporting rock by means of preferential flotation. Sand, limestone, dolomite, and other types of rock material will float on TBE, while minerals such as sphalerite, galena and pyrite will sink. A related compound, bromoform, is also sometimes used in these applications, however, TBE is more practical because of its wider liquid range and lower vapor pressure.[3] Acute TBE poisoning has been known to occur.[4]

References

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  3. 3.0 3.1 Organic based heavy liquids, heavyliquids.com
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