Methyl chloroformate

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Methyl chloroformate[1]
Skeletal formula of methyl chloroformate
Ball-and-stick model of the methyl chloroformate molecule
Names
IUPAC name
methyl carbonochloridate
Identifiers
79-22-1 YesY
ChemSpider 6337 YesY
Jmol 3D model Interactive image
Interactive image
PubChem 6586
  • InChI=1S/C2H3ClO2/c1-5-2(3)4/h1H3 YesY
    Key: XMJHPCRAQCTCFT-UHFFFAOYSA-N YesY
  • InChI=1/C2H3ClO2/c1-5-2(3)4/h1H3
    Key: XMJHPCRAQCTCFT-UHFFFAOYAT
  • O=C(Cl)OC
  • ClC(=O)OC
Properties
C2H3ClO2
Molar mass 94.49 g·mol−1
Density 1.223 g/mL
Boiling point 70 to 72 °C (158 to 162 °F; 343 to 345 K)
Vapor pressure {{{value}}}
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
YesY verify (what is YesYN ?)
Infobox references

Methyl chloroformate is the methyl ester of chloroformic acid. It is also known as methyl chlorocarbonate, and is an oily liquid with a colour that is anywhere from yellow to colorless. It is also known for its pungent odour. Methyl chloroformate, if heated, releases phosgene and produces toxic, corrosive fumes if it comes in contact with water.

Methyl chloroformate is used in organic synthesis for the introduction of the methoxycarbonyl functionality to a suitable nucleophile.

References

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